•Why it earns a slot
Why it earns a slot: it is the book that coined "best of all possible worlds" and staged the argument as a dream sequence instead of a syllogism, ending not with a proof but with a priest weeping with joy inside an infinite palace of alternate lives.
Leibniz sets out to prove that a perfectly good, all-knowing God still had to create a world with evil in it, and ends the book inside a dream of an infinite palace holding every version of a man who could have existed.
This distillation is written from the freely available original, which is always the better read when you have the time: Project Gutenberg.