•Why it earns a slot
Why it earns a slot: it is credited as the template for the modern detective novel, and Collins gets there through an unusual device, the mystery breaks open not from a sleuth's deduction alone but from literally re-drugging the suspect to force him to relive the crime.
A cursed yellow diamond disappears from a locked drawer on a country estate, and the detective solves it by drugging the prime suspect a second time to make him relive the crime.
This distillation is written from the freely available original, which is always the better read when you have the time: Project Gutenberg.