•Why it earns a slot
This 1751 pamphlet is the founding document of electrical science as a systematic discipline, introducing the single-fluid model of electricity, the terms positive and negative charge, the concept of conservation of charge in the Leyden jar, and the first practical proposal for the lightning rod, all derived directly from Franklin's own described experiments.
Franklin reports a series of electrical experiments conducted in Philadelphia, communicated as letters to London Fellow of the Royal Society Peter Collinson. He establishes the concepts of positive and negative charge, demonstrates that the force in a Leyden jar resides in the glass itself rather than the water or wire, and proposes that lightning is an electrical phenomenon. The work culminates in his suggestion that pointed iron rods connected to the ground could protect buildings and ships from lightning strikes.
This distillation is written from the freely available original, which is always the better read when you have the time: gutenberg.org.